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31.
S and Cl distribution between sodalite and fluid was experimentally studied at temperatures of 300–800°C and pressure of 0.5–3 kbar. It is demonstrated that S is preferably distributed into fluid in equilibrium with sodalite of the composition X S Sod > 0.05 throughout the whole temperature range. The distribution of S in the sodalite-fluid system is nonideal. An equation (derived from experimental data) is presented for evaluating the S mole fraction in fluid from the composition of sodalite at a known temperature. The S mole fractions in the fluid are evaluated for sodalite assemblages from nepheline syenites of the Lovozero Massif as being within the range of 0.036–0.23. The S mole fraction in the fluid is proved to increase with increasing mineral formation temperatures.  相似文献   
32.
This research tests the hypothesis that trace metals respond to the extent of reducing conditions in a predictable way. We describe pore water and sediment measurements of iron (Fe), manganese (Mn), vanadium (V), uranium (U), rhenium (Re), and molybdenum (Mo) along a transect off Washington State (USA). Sediments become less reducing away from the continent, and the stations have a range of oxygen penetration depths (depth to unmeasurable O2 concentration) varying from a few millimeters to five centimeters. When oxygen penetrates ∼1 cm or less, Fe is reduced in the pore waters but reoxidized near the sediment-water interface, preventing a flux of Fe2+ to overlying waters, whereas Mn oxides are reduced and Mn2+ diffuses to overlying waters. Both Re and U authigenically accumulate in sediments. Only at the most reducing location, where the oxygen penetrates 0.3 cm below the sediment-water interface, does the surface 30 cm of sediments become reducing enough to authigenically accumulate Mo.Stations in close proximity to the Juan de Fuca Ridge crest are enriched in Mn and Fe from hydrothermal plume processes. Both V and Mo clearly associate with Mn cycling, whereas U may be associating with either Mn oxides and/or Fe oxyhydroxides. Rhenium is uncomplicated by adsorption to Mn oxides and/or Fe oxyhydroxides, and Re accumulation in sediments appears to be due solely to the extent of reducing conditions. Therefore, authigenic sediment Re enrichment appears to be the best indicator for intermediate reducing conditions, where oxygen penetrates less than ∼1 cm below the sediment-water interface, when coupled with negligible authigenic Mo enrichment.  相似文献   
33.
Surface and subsurface water samples for 137Cs and 239,240Pu analysis were collected in the East Sea (Sea of Japan) during August 1993. The 137Cs levels of the surface waters are quite homogeneous in the East Sea (average = 3.1±0.2 mBq kg−1). The 239,240Pu levels vary from 6 to 10 μBq kg−1 in the surface. 239,240Pu to 137Cs ratios in the surface water are within 0.002 to 0.003. The East Sea may be regarded as a part of the North Pacific Ocean in terms of 137Cs dispersal in the surface, where the 137Cs contents of the surface seawater seem to be controlled primarily by the atmospheric input. However, since our sampling was made just two months prior to the widely publicized Russian dumping incident on the 17th October 1993, our measurements may provide background data to assess the immediate impact of the Russian dumping on the levels of 137Cs and 239,240Pu in the East Sea.  相似文献   
34.
In order to better understand the tectonic environment of the Korean Peninsula since Cretaceous, a paleomagnetic study was carried out on the Jinan Basin located in southwestern Korea. From the demagnetization of 597 samples, we found that remanence is carried by pyrrhotite and/or magnetite (black siltstone) and hematite (red siltstone), which is a common magnetic mineral assemblage of the rocks remagnetized in Early Tertiary in Korea. All the rock units recorded identical ancient geomagnetic field directions. In particular, paleodirections were better clustered in geographic coordinates, indicating a secondary origin. The presence of abundant silicates as inclusions within Fe-oxides and Fe-sulfides confirms the authigenic origin of the magnetic carriers, precipitated by fluid mediated chemical processes. Compilation of the Korean Cretaceous and Tertiary poles indicates that the Jinan Basin was remagnetized in the Early Tertiary age. In addition, comparison of the Korean Cretaceous and Tertiary poles with those from adjacent major terrains including China and Siberia reveals that a dominant feature of tectonic motions in Korea was a vertical-axis rotation. Sense of vertical-axis rotation was time-dependent, with clear distinction between clockwise rotation in Cretaceous and counter-clockwise rotation in Early Tertiary. Such differences in the mode of vertical axis rotation might be caused by the activities of basin-bounding strike–slip faults in Korea, possibly driven by the changes of subduction regime of the Kula-Pacific plate in Early Tertiary.  相似文献   
35.
For the appropriate management and restoration of rivers, isolated vegetation is often a practical means for improving stream habitat and ecology. The effect of a finite vegetation patch on flow and bed morphology in an open channel was investigated using laboratory experiments. The patch containing emergent and submerged vegetation was modeled using circular cylinders and located mid‐channel along a side wall. Several configurations of the patch and submergence ratio (i.e. water depth to the height of vegetation), and two flow conditions (i.e. below and above the sediment motion threshold) were considered. For flows below the sediment motion threshold, erosion occurred primarily on the opposite side of the patch and near the leading edge of the patch. The degree of scouring depth observed in both these regions was affected by the submergence ratio and it increased with the non‐dimensional flow blockage (i.e. the product of the patch density and width). In contrast, for flows above the sediment motion threshold, sediment accumulated within and around the patch due to a reduction in bed shear stress, which was strongly influenced by the flow blockage and the obstruction ratio (i.e. the ratio of patch width to channel width). The eroded area observed within the patch was consistent with the interior adjustment region where the deceleration and diversion of flow occurred through the patch. As the flow blockage increased or as the obstruction ratio decreased, the deposition rate within and behind the patch decreased. Furthermore, the deposition rate increased with an increase in the ratio of flow rate through the patch to total flow rate regardless of the submergence ratio. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
36.
We have developed a set of methods to detect meteor light traces captured by all-sky CCD cameras. Operating at small automatic observatories (stations), these cameras create a network spread over a large territory. Image data coming from these stations are merged in one central node. Since a vast amount of data is collected by the stations in a single night, robotic storage and analysis are essential to processing. The proposed methodology is adapted to data from a network of automatic stations equipped with digital fish-eye cameras and includes data capturing, preparation, pre-processing, analysis, and finally recognition of objects in time sequences. In our experiments we utilized real observed data from two stations.  相似文献   
37.
The depositional characters of densely dated turbidite successions originating from the southwestern margin of the Ulleung Basin reveal changes in high-resolution frequency, failing areas, and relative volumes of slope failures over the past 29.4 cal. ka. Between 29.4 and 19.1 cal. ka B.P., various thin- to very thick-bedded turbidites accumulated at an average recurrence interval of ca. 605 years. After 19.1 cal. ka B.P., turbidites were deposited with an average recurrence interval of 3,183 years, and their thickness abruptly decreased upward. These features suggest that various-scale slope failures occurred frequently during the eustatic lowering of sea level, and the frequency and relative volumes of slope failures suddenly decreased after sea level began to rise. When sea level was lowest (20.0–19.1 cal. ka B.P.), successive stacks of very thick turbidites can most likely be ascribed to larger-volume mass failures. An upward change from muddy to sandy turbidites around 21.4 cal. ka B.P. suggests that the failing areas retrograded from the muddy upper-middle slope to the sandy uppermost slope when sea level was nearly at its lowest. Based on these findings together with published evidence, frequent mass failures between 29.4 and 19.1 cal. ka B.P. were plausibly triggered by earthquakes, in combination with reduced hydrostatic pressure that promoted gas-hydrate dissolution during the eustatic lowering of sea level. These data on the frequency, scale, failing areas, and triggering causes of slope failures along the southwestern margin over the past 29.4 cal. ka, not documented in earlier studies, provide invaluable information to better understand the basin-scale characters and occurrences of latest Quaternary slope failures in the Ulleung Basin.  相似文献   
38.
As a part of an ongoing search for antioxidants frodm marine sources, antioxidant activities of 24 kinds of seaweeds (4 green algae, 8 brown algae, and 12 red algae) were investigated. The seaweeds were extracted by acetone/ dichloromethane and methanol, respectively. The antioxidant properties of both extracts were evaluated using four different activity tests, including degree of occurrence of intracellular reactive oxygen species (ROS), NO, lipid peroxidation, and GSH (glutathione) in mouse macrophage Raw 264.7 cells. The levels of intracellular reactive oxygen species (ROS) and GSH were measured using 2’,7’-dichlorofluorescin diacetate (DCF-DA) and monobromobimane as fluorescence probe, respectively. Moreover, the generation of NO and lipid peroxidation products were determined by each method based on the Griess reaction and TBARS assay. Solvent extracts from seaweeds such asScytosiphon lomentaria, Prionitis cornea, Laruencia okamurae,Callophyllis japonica, Sargassum horneri, Dictyopteris divaricat a,Lomentaria catenata, Corallina confuse, Ishige okamurae, andAhnfeltiopsis flabelliformi exhibited high antioxidant activities in cellular oxidizing systems.  相似文献   
39.
The experimental results of natural pyrochlore behavior in KF solutions in the presence of quartz at 550–850°C and 50–100 MPa are presented. It is shown that silicate matter (quartz) exerts a significant effect on pyrochlore solubility in aqueous solutions of fluorides of alkaline metals under hydrothermal conditions. This study of the fluid inclusions has revealed the occurrence of reactions of high-temperature hydrolysis of KF under the experimental conditions: KF + H2O = KOH + HF; in which case, the interaction with quartz SiO2 + 2KOH = K2SiO3 + H2O is followed by the formation of a silicate glass phase (an aqueous solution–melt). This phase of alkaline glass is a Nb concentrator (Nb2O5 up to 16 wt %). The coefficient of Nb distribution between the glass and the fluid is ≈500 (in favor of the glass). It is determined that the phase of the silicate solution–melt can serve as an effective concentrator of the ore component (Nb) at the last lowtemperature stages of crystallization of rare-metal granites.  相似文献   
40.
Numerical flow simulation of flush type intake duct of waterjet   总被引:1,自引:0,他引:1  
Waterjet propulsion system is widely used to thrust high speed marine vessels in excess of 30–35 knots by virtue of high propulsive efficiency, good maneuverability, and less vibration. Since, however, approximately 7–9% of the total power is lost in intake duct due to flow separation, nonuniformity, etc., detail understanding of flow phenomena occurring within intake duct is essential to reduce the power loss. The present work solved 3D incompressible RANS equations on multiblocked grid system of the flush type intake duct of waterjet. The numerical results of surface pressure distributions, velocity vectors, and streamlines were compared with experiments and good agreements were obtained for three jet velocity ratios. Strong suction flow through the inlet was shown and the vortex induced by the separation along the corner of the side wall was clearly shown. Flow separation on the lip was also observed. The location of stagnation point on the lip was well predicted, in accordance with PIV measurement.  相似文献   
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